Selective binding and removal of organic molecules in a flexible polymeric material with stretchable metallosalen chains.
نویسندگان
چکیده
A dynamic porous coordination network with a hydrophobic channel was assembled from stretchable 1D metallosalen polymer, which has the ability to recognize and, particularly, separate aromatic hydrocarbons from aliphatic mixtures with high selectivity.
منابع مشابه
Post-synthesis modification of a metal-organic framework to form metallosalen-containing MOF materials.
A series of metallosalen-based metal-organic frameworks (MOFs) have been prepared by the post-synthesis modification of Mn(III)SO-MOF, a Mn(3+)(salen)-based MOF. Treatment of Mn(III)SO-MOF with H(2)O(2) effects the removal of the Mn(3+) ions from the salen struts, which can then be remetalated with a variety of metal precursors to form isostructural MSO-MOF materials. The presence of the new me...
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ورودعنوان ژورنال:
- Chemical communications
دوره 16 شماره
صفحات -
تاریخ انتشار 2009